Dichloro­oxo(quinoline-8-thiolato-κ2 N, S)(triphenyl­phosphine oxide-κ O)rhenium(V) acetone solvate.

Autor:	Miyashita, Yoshitaro, Ohashi, Tetuya, Imai, Akiomi, Amir, Nagina, Fujisawa, Kiyoshi, Okamoto, Ken-ichi
Předmět:	RHENIUM compounds MOLECULES QUINOLINE ATOMS CHEMICAL bonds
Zdroj:	Acta Crystallographica: Section C (Wiley-Blackwell); Nov2005, Vol. 61 Issue 11, pm476-m478, 3p
Abstrakt:	The complex mol­ecule in the title compound, [Re(C9H6NS)Cl2O(C18H15OP)]·C3H6O, has distorted octa­hedral geometry. The Re=O bond occupies the position trans to the triphenyl­phosphine oxide O atom. The Re—Cl bond trans to the thiol­ate S atom is longer than that trans to the quinoline N atom, implying a stronger trans influence of the S atom. Intra- and inter­molecular π–π inter­actions are also observed between the π rings in the complex. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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