| Abstrakt: |
For various sample geometries (slabs, cylinders, spheres, hypercubes), de Gennes' boundary condition parameter b is used to study its effect upon the transition temperature T c of a superconductor. For b > 0 the order parameter at the surface is decreased, and as a consequence T c is reduced, while for b < 0 the order parameter at the surface is increased, thereby enhancing T c of a specimen in zero magnetic field. Exact solutions, derived by Fink and Haley ( Int. J. mod. Phys. B, 17 , 2171 (2003)), of the order parameter of a slab of finite thickness as a function of temperature are presented, both for reduced and enhanced transition (nucleation) temperatures. At the nucleation temperature the order parameter approaches zero. This concise review closes with a link established between de Gennes' microscopic boundary condition and the Ginzburg–Landau phenomenological approach, and a discussion of some relevant experiments. For example, applying the boundary condition with b < 0 to tin whiskers elucidates the increase of T c with strain. [ABSTRACT FROM AUTHOR] |
