Interpreting closed-loop learning control of molecular fragmentation in terms of wave-packet dynamics and enhanced molecular ionization.

Autor:	Cardoza, David, Baertschy, Mark, Weinacht, Thomas
Předmět:	MOLECULAR structure WAVE packets IONIZATION (Atomic physics) WAVES (Physics) SCISSION (Chemistry) LASERS
Zdroj:	Journal of Chemical Physics; 8/15/2005, Vol. 123 Issue 7, p074312, 6p, 6 Graphs
Abstrakt:	We interpret a molecular fragmentation experiment using shaped, ultrafast laser pulses in terms of enhanced molecular ionization during dissociation. A closed-loop learning control experiment was performed to maximize the CF3+/CH3+ production ratio in the dissociative ionization of CH3COCF3. Using ab inito molecular structure calculations and quasistatic molecular ionization calculations along with data from pump-probe experiments, we identify the primary control mechanism which is quite general and should be applicable to a broad class of molecules. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
Externí odkaz:	Zobrazit plný text záznamu