Windmill grass (Chloris spp.) as a non‐wood source of cellulose for reinforcement of starch films.

Autor: Flores‐Martínez, N. L., Cruz‐Rodríguez, J. J., Arredondo‐Tamayo, B., Hernández‐Varela, J. D., Chanona‐Pérez, J. J., Gallegos‐Cerda, S. D., Hernández‐Hernández, H. M., Jarquín‐Enríquez, L.
Zdroj: Polymer Composites; 12/20/2024, Vol. 45 Issue 18, p16898-16915, 18p
Abstrakt: Nowadays, non‐timber sources are of greater interest as they avoid deforestation and the pollution which occurs with cellulose obtention. An emerging alternative is using weeds such as windmill grass (Chloris spp.) to isolate cellulose since the plant grows in large quantities near crops or landfills used for farming. The present study aims to explore windmill grass as an alternative source of cellulose for applications as reinforcement in biopolymeric matrices. Treatment was conducted using the peroxyformic pulping method, varying the formic acid (FA) and hydrogen peroxide (HP) concentration to obtain an optimum cellulose extraction condition. The isolated celluloses were analyzed for chemical composition, yield, chemical functionality, crystallinity, and morphology. The optimum pulping condition (FA = 87.5%, HP = 3%) shows the gradual removal of non‐cellulosic components by microscopy. X‐ray diffraction analysis revealed a high crystallinity index (89.63%) with a characteristic cellulose type I pattern. To evaluate the reinforced effect of Chloris spp. celluloses, film formulations were made using sweet potato starch, glycerol, and cellulose at different concentrations (2.5, 5.0, and 7.5% w/w). The films' mechanical, physicochemical, and thermal properties were measured, and results indicate that adding cellulose fibers significantly improves these properties of sweet potato starch films, revealing further applications and non‐wood windmill grass added value with potential applications in the packaging sector. Highlights: Windmill grass (Chloris spp.) is presented as a non‐wood source of cellulose.The peroxyformic method is reported as a less polluting cellulose extraction process.Optimal cellulose pulp presents enhanced physicochemical properties after bleaching.Cellulose‐reinforced sweet potato starch films exhibit a stable biopolymeric matrix.The films produced show enhanced water barrier and mechanical/thermal properties. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
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