Integrated effects of water conditions and aging on chromium speciation and availability in two paddy soils spiked with hexavalent chromium.

Autor: Wang, Zhilin, Feng, Weiming, Zhang, Jianming, Chang, Minghui, Ma, Yibing, Li, Helian
Předmět:
Zdroj: Environmental Pollutants & Bioavailability; Dec2024, Vol. 36 Issue 1, p1-10, 10p
Abstrakt: Indoor incubation experiment was conducted under flooding (FD), 100% field capacity (100% FC), and alternating wetting and drying (AWD) conditions for 90 days using Guangdong (GD) and Jiangxi (JX) paddy soils spiked with hexavalent chromium [Cr(VI)]. The chromium speciation and availability were investigated usingsequential extraction, diethylene triamine pentaacetic acid (DTPA) leaching, and alkali solution extraction methods. The concentrations of Cr(VI), acid-extractable Cr and DTPA-Cr were reduced by 72%–89%, 48%–81%, and 42%–98%, respectively, at 90 d compared with 1 d. The sequence for acid-extractable Cr and DTPA-Cr concentrations was 100% FC>AWD>FD. While, it was AWD>100% FC>FD for Cr(VI) concentrations. Acid-extractable Cr, DTPA-Cr, and Cr(VI) concentrations in JX soil were higher compared with GD soil. The changes of DTPA-Cr concentrations were well fitted by Elovich kinetic model. These findings revealed water management and aging greatly affected chromium speciation and availability, having potential implications for sustainable agriculture and human health. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index