| Autor: |
Ziółkowska, Aleksandra, Kruczyński, Tomasz, Gudat, Dietrich, Ponikiewski, Łukasz |
| Zdroj: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 12/28/2024, Vol. 53 Issue 48, p19107-19111, 5p |
| Abstrakt: |
We synthesized phosphanylphosphaalkenes (biph)2C＝P-P(tBu)2 (2), Ph2C＝P-P(NEt2)2 (3), and (biph)2C＝P-P(NEt2)2 (4). The diaminophosphanyl derivatives reversibly dimerize head-to-head and react with a ruthenium complex, leading to P–P bond activation and the formation of a bridging phospaalkene complex under mild conditions. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
|
