CHEMOSELECTIVE METAL FREE DEALLYLATION OF α-ALLYL-PHENYL-CARBOXYLIC ESTERS UNDER REDUCTION CONDITION.

Autor: Nawghare, Beena R., Joshi, Rekha R., Lokhande, Pradeep D.
Předmět:
Zdroj: Bulletin of the Chemical Society of Ethiopia; 2025, Vol. 39 Issue 1, p131-139, 9p
Abstrakt: A simple and efficient method for chemoselective deallylation of -COO-allyl group in presence of C-allyl group has been developed. C-allyl cleavage of a-methylene compounds was successfully completed by refluxing with excess sodium borohydride in methanol. The reagent's stability, ready availability and ease of handling encourage its usage for deallylation. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index