Exploring the effect of pressure on the crystal structure and caloric properties of the molecular ionic hybrid [(CH3)3NOH]2[CoCl4].

Autor: Dafonte-Rodríguez, Pedro, Delgado-Ferreiro, Ignacio, García-Ben, Javier, Ferradanes-Martínez, Angel, Gelpi, María, Walker, Julian, McMonagle, Charles James, Castro-García, Socorro, Señarís-Rodríguez, María Antonia, Bermúdez-García, Juan Manuel, Sánchez-Andújar, Manuel
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Zdroj: Chemical Communications; 12/11/2024, Vol. 60 Issue 95, p14065-14068, 4p
Abstrakt: The hybrid metal halide [(CH3)3NOH]2CoCl4 exhibits a first-order phase transition at T ∼ 343 K. Its crystal structure and caloric properties respond significantly to moderate pressures (1–1000 bar), demonstrating potential for applications in emerging solid-state refrigeration technologies. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index