Two novel fluorescence "turn on" probes based on pyrazolone and thiosemicarbazide for selective recognition of In3+.

Autor: Zhang, Heming, Lu, Fengyuan, Che, Yuanyuan, Li, Xiaojuan
Předmět:
Zdroj: New Journal of Chemistry; 12/14/2024, Vol. 48 Issue 46, p19614-19620, 7p
Abstrakt: Highly selective fluorescence "turn on" probes (PTSC and TSC) based on a conjugate of pyrazolone and thiosemicarbazide were devised and synthesized. The structure was verified by 1H NMR, 13C NMR and HR-MS. The probe demonstrated effectiveness, high selectivity, and specificity to capture indium ions. The fluorescence intensity of the probe solution was significantly enhanced by the addition of In3+. The 1 : 1 complexation between In3+ and probe PTSC was confirmed by Job's plot, and the limit of detection (LOD) of PTSC for In3+ was calculated to be 2.01 × 10−7 M. Furthermore, PTSC was produced as test strips, which have enormous potential to detect In3+ ions in the environment. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index