Front Cover: Photoinduced Enantioselective Triplet Radical Reaction on Metal: Copper‐Catalyzed Conjugate Addition of Acylsilanes to α,β‐Unsaturated Ketones and Aldehydes (Chem. Eur. J. 65/2024).

Autor:	Masuda, Yusuke, Ueda, Yusuke, Sueki, Aiko, Shimosato, Junpei, Nishimura, Kousei, Gao, Min, Hasegawa, Jun‐ya, Sawamura, Masaya
Předmět:	STATE bonds COPPER RADICALS (Chemistry) KETONES ALDEHYDES
Zdroj:	Chemistry - A European Journal; 11/21/2024, Vol. 30 Issue 65, p1-1, 1p
Abstrakt:	The article in Chemistry - A European Journal discusses a photoinduced copper‐catalyzed enantioselective conjugate addition of acylsilanes to α,β‐unsaturated ketones and aldehydes. The process involves metal‐to-ligand charge‐transfer excitation of an alkene‐bound acylcopper intermediate to generate a triplet β‐radical‐C‐enolate‐CuII‐acyl complex, leading to C−C bond formation in the copper coordination sphere. The research highlights the potential of triplet excited state C−C bond formation as a valuable synthetic strategy. The study was conducted by a team of researchers including Yusuke Masuda, Yusuke Ueda, Aiko Sueki, Junpei Shimosato, Kousei Nishimura, Min Gao, Jun‐ya Hasegawa, and Masaya Sawamura. [Extracted from the article]
Databáze:	Complementary Index
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