| Autor: |
Tölke, Katharina, Neumann, Beate, Stammler, Hans‐Georg, Hoge, Berthold |
| Předmět: |
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| Zdroj: |
Chemistry - A European Journal; 11/21/2024, Vol. 30 Issue 65, p1-5, 5p |
| Abstrakt: |
The reaction of [Ga(C2F5)3(FSiMe3)] with chlorotrimethylsilane leads to the selective substitution of the α‐fluorine atoms by chlorine atoms and thus to the formation of [Ga(CCl2CF3)3(FSiMe3)]. The corresponding chlorogallate ion, [Ga(CCl2CF3)3Cl]−, could be isolated and structurally characterized as its tetraphenylphosphonium salt. The catalytic potential of [Ga(CCl2CF3)3(FSiMe3)] was demonstrated via the chlorodefluorination of Me3SiCF3, 2,2‐difluoropropane and [PPh4][Ga(C2F5)4]. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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