| Autor: |
Rogers, Cory H., Pradeep, Anu, Galiano, Layla A., Kelley, S. Ariel, Varadharajan, Ramkumar, Belmore, Ken, Whitt, Logan M., Li, Yanmei, Champagne, Pier Alexandre, Ramamurthy, Vaidhyanathan, Blackstock, Silas C. |
| Zdroj: |
Chemical Communications; 12/7/2024, Vol. 60 Issue 94, p13899-13902, 4p |
| Abstrakt: |
ortho-Nitrosocumene (o-NC) exhibits dynamic N,N bonding, interchanging monomer and E/Z-azodioxide dimer structures, the extent of which depends on the environment. As a solid, o-NC is a Z-dimer; in organic solvent, the monomer is favored; and in water, dimers are favored. A supramolecular assembly of o-NC is observed as a separate species by NMR in water, shown to be a novel nanometer-sized aggregate containing ∼2000 molecules. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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