| Autor: |
Ding, Yang, Ke, Jie, Zhang, Wenbin, Li, Bin, He, Chuan |
| Předmět: |
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| Zdroj: |
Chemical Communications; 12/4/2024, Vol. 60 Issue 93, p13734-13737, 4p |
| Abstrakt: |
A highly efficient rhodium-catalyzed asymmetric hydrosilylation of aldehydes, ketones, and α,β-unsaturated ketones with dihydrosilanes is developed, that allows the rapid assembly of a variety of Si-stereogenic alkoxysilanes and silyl enol ethers in good yields and enantioselectivities under mild conditions. The applicability of this methodology was demonstrated by a series of stereospecific transformations to construct diverse Si-stereogenic derivatives. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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