| Autor: |
Velisoju, Vijay K., Ramos‐Fernández, Enrique V., Kancherla, Rajesh, Ahmad, Rafia, Pal, Kuntal, Mohamed, Hend, Cerrillo, Jose L., Meijerink, Mark J., Cavallo, Luigi, Rueping, Magnus, Castaño, Pedro |
| Předmět: |
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| Zdroj: |
Angewandte Chemie; 11/25/2024, Vol. 136 Issue 48, p1-10, 10p |
| Abstrakt: |
Our study unveils a pioneering methodology that effectively distributes Pd species within a zeolitic imidazolate framework‐8 (ZIF‐8). We demonstrate that Pd can be encapsulated within ZIF‐8 as atomically dispersed Pd species that function as an excited‐state transition metal catalyst for promoting carbon–carbon (C−C) cross‐couplings at room temperature using visible light as the driving force. Furthermore, the same material can be reduced at 250 °C, forming Pd metal nanoparticles encapsulated in ZIF‐8. This catalyst shows high rates and selectivity for carbon dioxide hydrogenation to methanol under industrially relevant conditions (250 °C, 50 bar): 7.46 molmethanol molmetal−1 h−1 and >99 %. Our results demonstrate the correlations of the catalyst structure with the performances at experimental and theoretical levels. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
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