| Autor: |
Reibenspies, Joseph, Small, Nadia, Bhuvanesh, Nattamai, Chiarella, Gina, Salazar, Vivian, Pery, Bréayshia, Smith, Rukiyah, Toole, Deja, Hewage, Shamika, Fernando, Harschica, Reinheimer, Eric |
| Předmět: |
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| Zdroj: |
Acta Crystallographica Section E: Crystallographic Communications; Nov2024, Vol. 80 Issue 11, p1157-1160, 9p |
| Abstrakt: |
The crystal structure of the title compound, [Ni(C8H20N4)(NO3)]NO3, at room temperature, has monoclinic (P21/n) symmetry. The structure displays inter-molecular hydrogen bonding. The nickel displays a distorted bipyramidal geometry with the symmetric bidentate bonded nitrate occupying an equatorial site. The 1,4,7,10-tetraazacyclododecane (cyclen) backbone has the [4,8] configuration, with three nitrogen-bound H atoms directed above the plane of the nitrogen atoms towards the offset nickel atom with the fourth nitrogen-bound hydrogen directed below from the plane of the nitrogen atoms. The nitrate anion O atoms are seen to hydrogen bond to the H atoms bound to the N atoms of the ligand. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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