Influence of 1-methyl-3-octylimidazolium chloride on MIL-53(Al) crystallinity and particle size.

Autor: Wang, Oliver, Vadlamudi, Pranavsai, Jang, Victoria, Hoadley, Andrew, Ortoll-Bloch, Amnon G.
Zdroj: Physical Chemistry Chemical Physics (PCCP); 11/28/2024, Vol. 26 Issue 44, p27861-27866, 6p
Abstrakt: Little is known about ionic liquids as MOF crystallization additives. We investigate the role of 1-methyl-3-octylimidazolium chloride (OmimCl) in MIL-53(Al) hydrothermal synthesis. Higher crystallinities and particle sizes with 0.05–0.50% v/v OmimCl suggest preferential growth along [001]. With 1.0–10% v/v OmimCl, missing linkers and lower crystallinities indicate arrested growth. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index