Gold nanoparticle-decorated amorphous carbon for oxidative cyclization of anthranilamide and aryl alcohols.

Autor: Nguyen, The Thai, Nguyen, Huyen-Tran Thi, Nguyen, Thu Anh, Vo, Khuong Quoc, Tran, Phuong Hoang
Předmět:
Zdroj: Dalton Transactions: An International Journal of Inorganic Chemistry; 11/28/2024, Vol. 53, p17976-17988, 13p
Abstrakt: Herein, gold nanoparticle-decorated amorphous carbon (Au/AC) was prepared by reducing chloroauric acid and layering it on amorphous carbon. The characteristics of Au/AC were examined using FT-IR, XRD, TGA, SEM, EDS, and XPS. To assess its catalytic activity, Au/AC was tested in a reaction involving anthranilamide and benzyl alcohol at 110 °C for 24 hours. This reaction yielded various 2-phenylquinazolin-4(3H)-one derivatives in moderate to good yields (44–80%). Furthermore, control experiments were conducted to demonstrate the oxidation and cyclization functions of Au/AC. Noteworthy aspects of this approach included the ease of isolating Au/AC (via recrystallization) and the ability to recycle it. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index