A d 10 -Cd Cluster Containing Sandwich-Type Arsenotungstate Exhibiting Fluorescent Recognition of Carcinogenic Dye in Methanol.

Autor:	Wang, Feng, Ma, Xiang, Li, Haodong, Zhao, Ziqi, Zhang, Lele, Zhao, Yutong, Su, Haipeng, Wang, Zeqi, Li, Changchun, Hua, Jiai
Předmět:	X-ray powder diffraction POLYCYCLIC aromatic hydrocarbons X-ray photoelectron spectroscopy CARCINOGENS MOLECULES
Zdroj:	Molecules; Nov2024, Vol. 29 Issue 21, p5193, 12p
Abstrakt:	A d10-Cd cluster containing sandwich-type arsenotungstate [C3H12N2]6[Cd4Cl2(B-α-AsW9O34)2] was synthesized and its structure characterized through elemental analyses, X-ray powder diffraction (XRPD), IR spectroscopy, X-ray photoelectron spectroscopy (XPS), and single-crystal X-ray diffraction. The X-ray analysis revealed that the molecular unit of the compound consists of a captivating tetra-Cd-substituted sandwich-type polyoxoanion, accompanied by six elegantly protonated 1,2-diaminopropane as counter ions. The further novelty of the tetranuclear cadmium cluster lies in its occupied chlorine atom sites. This makes it highly susceptible to coordinate reactions with nitrogen on polycyclic aromatic hydrocarbons, thereby exhibiting different fluorescent signals that facilitate the identification and detection of these carcinogenic substances in methanol. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
Externí odkaz:	Zobrazit plný text záznamu Plný text ve formátu HTML
Nepřihlášeným uživatelům se plný text nezobrazuje	K zobrazení výsledku je třeba se přihlásit.