| Autor: |
Zhang, Qing-Bao, Li, Feng, Pan, Bin, Zhang, Shanshan, Yue, Xiang-Guo, Liu, Qiang |
| Předmět: |
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| Zdroj: |
Green Chemistry; 11/21/2024, Vol. 26 Issue 22, p11083-11105, 23p |
| Abstrakt: |
Bicyclo[1.1.0]butanes, as structurally unique compounds with high strain energy and diverse chemical properties, are becoming increasingly popular building blocks in organic and pharmaceutical chemistries. Strain-release transformation of bicyclo[1.1.0]butanes has received great attention from chemists as it is atom- and step-economical, and significant achievements have been made in this field. Visible-light photocatalysis, with its green and sustainable properties, enriches the strain-release strategy through an electron transfer or energy transfer pathway under mild conditions. In this review, we highlight the latest advancements in visible-light-induced strain-release reactions of bicyclobutanes, with a particular focus on the reaction mechanism. Organization of the content follows a subdivision based on reaction and product classes. Advances in obtaining unique chemical architectures continue to be breakthroughs in this fascinating field of research. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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