Non-monotonic lattice expansion in zeolitic imidazolate frameworks during heating.

Autor: Winters, Wessel M. W., Madsen, Rasmus S. K., Magdysyuk, Oxana V., Yue, Yuanzheng
Předmět:
Zdroj: Chemical Communications; 11/21/2024, Vol. 60 Issue 90, p13275-13278, 4p
Abstrakt: The effect of substituting linkers with two additional methyl groups for conventional benzimidazolate on the thermal expansion behaviour of ZIF-62 was investigated by high-energy in situ X-ray diffraction. Increased structural integrity was observed with the addition of methyl groups, and variable anisotropic thermal expansion was discovered in ZIF-62 and its derivative. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index