Low-valent group 6 metals/Al(C6F5)3 donor–acceptor systems for CO2 activation and cleavage.

Autor: Escomel, Léon, Le Dé, Quentin, Benonie, Maxime, Vendier, Laure, Simonneau, Antoine
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Zdroj: Chemical Communications; 11/21/2024, Vol. 60 Issue 90, p13235-13238, 4p
Abstrakt: Donor–acceptor systems for CO2 activation combining a formally zero-valent group 6 metal as the donor with the Lewis acid Al(C6F5)3 (AlCF) are reported. They were obtained from AlCF adducts of N2-complexes by N2-to-CO2 substitution. One species was capable of C–O cleavage. The boron analogues led to intractable mixtures. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index