An aniline-bridged bis(pyrazolyl)alkane ligand for dizinc-catalysed ring-opening polymerization.

Autor: Naik, Pratyush K., Zipeng Gu, Comito, Robert J.
Předmět:
Zdroj: Dalton Transactions: An International Journal of Inorganic Chemistry; 11/21/2024, Vol. 53 Issue 43, p17443-17447, 5p
Abstrakt: We report an aniline ligand (1) with two bis(pyrazolyl)alkane arms, and its cationic, dizinc complexes. XRD, NMR, and modelling of the dizinc complexes resulted in an unprecedented, dynamic μ-anilide core. Compared with published μ-phenolate analogues, our μ-anilide complexes show higher activity and divergent counterion trends in ring-opening polymerization of rac-lactide. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index