Photo-thermo synergistic permanganate decomposition over a hydrolytically stable Co(II)-MOF.

Autor: Quan-Quan Li, Huan-Xi Wang, Yi Deng, Si-Yu Chen, Yang Chen, Shi-Jie Cao, Qing-Wen Ye, Jing Bai, Hua Liu
Předmět:
Zdroj: Dalton Transactions: An International Journal of Inorganic Chemistry; 11/21/2024, Vol. 53 Issue 43, p17687-17693, 7p
Abstrakt: Photo-thermo catalysis that combines photo- and thermo-catalysis has emerged as an attractive approach for effective and economical elimination of pollutants. Herein, we fabricated a robust, highly water stable 2D Co(II)-MOF photo-thermo catalyst towards the decomposition of permanganate anions. It has been demonstrated that Co(II)-MOF exhibits excellent catalytic capacity, good selectivity and incredible reusability for degrading MnO4-. The reaction rate of the process was investigated for thermo-photo vs. thermo/photo processes to provide conclusive evidence that Co(II)-MOF shows a strong synergistic use as both an energy source and Lewis acid. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index