| Autor: |
Naulakha, Pragya, Kaushik, Priyanka, Raghavaiah, Pallepogu, Supriya, Sabbani |
| Předmět: |
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| Zdroj: |
ChemistrySelect; 11/4/2024, Vol. 9 Issue 41, p1-7, 7p |
| Abstrakt: |
The Strandberg polyoxometalate (POM) metallogel Na4(H3O)2[(O2CC2H4PO3)2Mo5O15] (1) was synthesized in which the Strandberg cluster is functionalized by phosphonocarboxylate. The POM gel shows reversible sol to gel transition and gel to gel transition. The multiphase visual transitions between three states as a function of temperature and solvent are scarcely reported. The gel is characterized by temperature‐dependent and frequency‐dependent rheological studies and corresponding xerogels were characterized by FT‐IR, PXRD, FE‐SEM, EDX, TEM, and 31P NMR techniques. The stabilization of gel or obtaining single crystals from the same reaction mixture can be tuned by choice of counter cation. The single crystals of compound Cs14[(HO2CC2H4PO3)2Mo5O15]3·2Cl·10H2O (2) are obtained on addition of CsCl to compound 1 reaction mixture. Compound 2 is characterized by single crystal X‐ray diffraction. The compound 2 crystallizes in I2/a space group with unit cell parameters of a = 24.2415(16) Å, b = 10.4542(6) Å, c = 42.687(3) Å, α = 90°, β = 94.791°(3), and γ = 90°. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
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