Reaction of 6Н-5-(4-Fluorophenyl)-3-(2-pyridyl)-1,2,4-triazine with 4,5-Difluoro-1,2-dehydrobenzene.

Autor:	Rammohan, A., Krinochkin, A. P., Sayfutdinova, Yu. M., Shtaitz, Y. K., Potapova, S. S., Slepukhin, P. A., Gaviko, V. S., Kopchuk, D. S., Zyryanov, G. V., Chupakhin, O. N.
Předmět:	X-ray diffraction INDOLE INDOLE compounds
Zdroj:	Russian Journal of General Chemistry; Sep2024, Vol. 94 Issue 9, p2255-2263, 9p
Abstrakt:	The reaction of C6-unsubstituted 5-aryl-3-(2-pyridyl)-1,2,4-triazine with generated in situ difluoroaryne intermediate (4,5-difluoro-1,2-dehydrobenzene), previously unused for this aim, was studied. New transformations of the 1,2,4-triazine nucleus were discovered, which lead, along with the domino transformation product (10-(1,2,3-triazole-3-yl)pyrido[1,2-a]indole) natural for this transformation, to the formation of unexpected products, namely 1,3,5-tris-substituted 1,6-dihydro-1,2,4-triazin-6-ol and 1H-1,2,4-triazole. The structure of the products was confirmed by physicochemical methods, including X-ray diffraction analysis. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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