| Autor: |
Tong, Zekun, Dong, Shaoqiang |
| Zdroj: |
Chemical Communications; 11/11/2024, Vol. 60 Issue 87, p12766-12769, 4p |
| Abstrakt: |
We report the synthesis of macrocyclic cyclobis[7,8-(para-quinodimethane)-3,7-(9-(p-tolyl)-9H-carbazole)] CBQCz. We found that CBQCz showed temperature-dependent and four-electron oxidative conformation changes. Both CBQCz and CBQCz4+ possess boat-to-boat conformation inversions. The smaller inverted energy and less curved structure of CBQCz4+ are due to the conjugated effect of tetracations. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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