Reactions of phosphorus (iv) and orthocarboxylic acid esters with benzal and benzyl halides: pathways and catalysis.

Autor:	Gazizov, M. B., Khairullin, R. A., Ivanova, S. Yu., Karimova, R. F., Nuriakhmetov, B. D., Khairullina, O. D., Shaikhutdinova, L. R., Gazizova, N. N.
Předmět:	BENZYL halides BENZYL compounds ZINC chloride ESTERS PHOSPHORUS
Zdroj:	Russian Chemical Bulletin; Sep2024, Vol. 73 Issue 9, p2693-2700, 8p
Abstrakt:	The main pathway of the reaction of benzal and benzyl halides with phosphorus(iv) acid esters followed the dehalophosphonyl/phosphinyl(oxylation) course and led to the corresponding carbonyl-containing compounds or benzyl esters. A new reaction between α-chloro ethers and O-alkyl diethylphosphinates was discovered. The reactions of benzyl halides with esters of phosphorus(iv) and orthocarboxylic acids were catalyzed by anhydrous zinc chloride. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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