Reaction of bismuth(iii) chloride with N-(5,6-dihydro-4H-1,3-thiazin-2-yl)benzamide.

Autor:	Trofimova, T. P., Tafeenko, V. A., Borodkov, A. S., Proshin, A. N., Evdokimov, A. A., Orlova, M. A.
Předmět:	INDUCTIVELY coupled plasma atomic emission spectrometry ELECTRON spectroscopy NUCLEAR magnetic resonance spectroscopy MASS spectrometry CHARGE exchange
Zdroj:	Russian Chemical Bulletin; Sep2024, Vol. 73 Issue 9, p2660-2666, 7p
Abstrakt:	A new bismuth complex with the N-(5,6-dihydro-4H-1,3-thiazin-2-yl)benzamide ligand (L = C11H13N2OS) was synthesized for further medical use. The complex and the ligand exhibit anticancer activity. The structure of the complex was characterized by NMR spectroscopy, inductively coupled plasma atomic emission spectroscopy (ICP-AES), and laser-induced electron transfer desorption/ionization (LETDI) mass spectrometry. The Bi: L ratio is 1: 1; the components are connected by an ionic (ion-dipole) interaction. The reaction of bismuth(iii) chloride with ligand hydrobromide (L•HBr) affords the complex {(C11H13N2OS)3[Bi2Cl9]}. The composition of this complex was confirmed by X-ray diffraction, ICP-AES, and LETDI methods. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
Externí odkaz:	Zobrazit plný text záznamu Full text from SpringerLink