| Autor: |
Hansen, Per-Anders, Baba, Elbruz Murat |
| Předmět: |
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| Zdroj: |
Journal of Applied Physics; 10/21/2024, Vol. 136 Issue 15, p1-7, 7p |
| Abstrakt: |
Photochromic yttrium oxyhydride (YHO) shows a very attractive color-neutral darkening upon photoactivation. However, the exact defect or state responsible for the visible light absorption or the mechanism for its creation is not fully understood. This makes it challenging to optimize and modify the material. In this work, we have investigated the relationship between photon absorption and darkening profile into a YHO film. The extinction coefficient k(λ) is obtained from spectroscopic ellipsometry, and the expected photon absorption profile is calculated. This is then compared to transmittance data during photodarkening by short-wavelength UV (254 nm). Our results show that the darkening is not homogeneous through the film, showing that photon absorption and darkening are positionally correlated, yet we show that the darkening stretches further into the film than the calculated photon absorption. A homogeneously darkened sample cannot always be assumed when assessing optical transmittance, absorbance, and ellipsometry data. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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