Hypervalent zinc(I) complexes with an NNNN-macrocycle: C–H bond activation across the zinc(I)–zinc(I) bond.

Autor: Mahawar, Pritam, Rajeshkumar, Thayalan, Spaniol, Thomas P., Maron, Laurent, Okuda, Jun
Předmět:
Zdroj: Chemical Communications; 10/14/2024, Vol. 60 Issue 80, p11359-11362, 4p
Abstrakt: Hetero- and homoleptic dinuclear zinc(I) complexes containing the macrocycle Me4TACD (N,N′,N′′,N′′′-1,4,7,10-tetramethylcyclododecane) were prepared; the heteroleptic complex [(Me4TACD)Zn–ZnCp*]+ reacted with activated hydrocarbons R–H (R = CH2CN, C≡CPh) to give the corresponding hydrocarbyl zinc(II) complexes [(Me4TACD)ZnR]+. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index