| Autor: |
Qiao, Yuyan, Pan, Yanqiu, Fan, Wenjun, Long, Guifa, Zhang, Fuxiang |
| Předmět: |
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| Zdroj: |
Chemical Communications; 10/14/2024, Vol. 60 Issue 80, p11287-11290, 4p |
| Abstrakt: |
NiFe-based oxyhydroxides are promising electrocatalysts for the oxygen evolution reaction (OER) in alkaline media, but further enhancing their OER performance remains a significant challenge. Herein, we in situ incorporated polyoxometalates into NiFe oxyhydroxides to form a homogeneous/heterogeneous hybrid material, which induces the electronic interaction between Ni, Fe and Mo sites, as revealed by a variety of characterization experiments and theoretical calculations. The resulting hybrid electrocatalyst delivers a low overpotential of 203 mV at 10 mA cm−2 and a TOF of 2.34 s−1 at 1.53 V in alkaline media. This work presents a critical step towards developing high-performance OER catalysts by constructing metal–POM hybrids. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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