Strong size sieving effect in a rigid oxalate-based metal–organic framework for selective lithium extraction.

Autor: Huang, Wenhao, Chen, Zhonghang, Cheng, Peng, Shi, Wei
Předmět:
Zdroj: Chemical Communications; 10/25/2024, Vol. 60 Issue 83, p11972-11975, 4p
Abstrakt: An oxalate-based metal–organic framework Eu-C2O4 was synthesized at gram-scale and studied as a selective adsorbent for Li+ ions, and it exhibited high Li+/Na+ selectivity in aqueous solution. A detailed mechanism study revealed that the key was the well-matched chelating sites of the framework for Li+ ion extraction. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index