| Autor: |
Kumar, Viksit, Dongre, Sangram D., Venugopal, Geethu, Narayanan, Aswini, Babu, Sukumaran Santhosh |
| Předmět: |
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| Zdroj: |
Chemical Communications; 10/25/2024, Vol. 60 Issue 83, p11944-11947, 4p |
| Abstrakt: |
The inherent helical chirality and improved π-stacking capabilities endow helicenes with fascinating photophysical characteristics when decorated with lateral π-extensions. Here, we report the synthesis and physicochemical characterization of expanded hetero[6]helicenes fused with thiadiazole and selenadiazole rings at the helical ends. Comparing these heterohelicenes revealed the impact of the heteroatom-embedded aromatic rings on the excited state and redox features. A small structural variation of the terminal rings from thiadiazole to selenadiazole caused a striking change in the heterohelical nanographenes. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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