Targeted design of heterotrimetallic 1-D coordination polymers based on functionalized metallocenes featuring antibacterial activity.

Autor: Uvarova, Marina A., Shmelev, Maxim A., Bekker, Olga B., Lutsenko, Irina A., Nefedov, Sergey E., Eremenko, Igor L.
Předmět:
Zdroj: New Journal of Chemistry; 10/28/2024, Vol. 48 Issue 40, p17391-17395, 5p
Abstrakt: Using (bis)diethoxyphosphoryl ferrocene [Fc(O=P(OEt)2)2] and transition metal carboxylates – [M2(μ-OOCR)4(CH3CN)2], M = CuII, R = tBu, (C5H4)Mn(CO)3 (Cym) or [M3(μ-OOCR)6(CH3CN)2], M = NiII, CoII, R = Cym, a series of heterometallic polymers with metal cores {Cu2Fe}n (1), {Cu2Mn4Fe}n (2) {Ni2Mn4Fe}n (3), and {Co2Mn4Fe}n (4) were obtained under mild conditions. Compounds 1 and 2 showed antibacterial activity against a Mycobacterium smegmatis strain in vitro. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index