| Autor: |
Sahoo, Sathi, Dinda, Tarun Kumar, Mal, Prasenjit |
| Předmět: |
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| Zdroj: |
Chemistry - A European Journal; 10/11/2024, Vol. 30 Issue 57, p1-11, 11p |
| Abstrakt: |
In this work, we used photoinert anhydrous cerium(III) chloride, to form a transient charge‐transfer (CT) complex with NXS (N‐bromosuccinimide or NBS and N‐iodosuccinimide or NIS) in acetonitrile. These transient CT complexes acted as a semi‐heterogeneous photocatalyst. These complexes allowed the Ce(III) ions to absorb light, turning them into strong electron donors that transferred electrons to NXS. This created halide radicals from NXS radical anions, helping to turn N‐propargylamides into oxazole aldehydes. Experiments with DMPO and spin‐trapping showed that a radical‐based mechanism followed a single electron transfer (SET) pathway. Notably, CeCl3 was reused after the reaction without much decomposition, as it was regenerated and separated through simple filtration. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
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