| Autor: |
He, Xiao, Zheng, Xuan, Guo, Shuwen, Zeng, Lewei, Chen, Ting, Yang, Bohan, Xiao, Shupei, Wang, Qiongqiong, Li, Zhiyuan, You, Yan, Zhang, Shaojun, Wu, Ye |
| Předmět: |
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| Zdroj: |
Atmospheric Chemistry & Physics; 2024, Vol. 24 Issue 18, p10655-10666, 12p |
| Abstrakt: |
The advancement of analytical techniques, such as comprehensive two-dimensional gas chromatography coupled with mass spectrometry (GC × GC–MS), enables the efficient separation of complex organics. Developing innovative methods for data processing and analysis is crucial to unlock the full potential of GC × GC–MS in understanding intricate chemical mixtures. In this study, we proposed an innovative method for the semi-automated identification and quantification of complex organic mixtures using GC × GC–MS. The method was formulated based on self-constructed mass spectrum patterns and the traversal algorithms and was applied to organic vapor and aerosol samples collected from the tailpipe emissions of heavy-duty diesel vehicles and the ambient atmosphere. Thousands of compounds were filtered, speciated, and clustered into 26 categories, including aliphatic and cyclic hydrocarbons, aromatic hydrocarbons, aliphatic oxygenated species, phenols and alkylphenols, and heteroatom-containing species. The identified species accounted for over 80 % of all the eluted chromatographic peaks at the molecular level. A comprehensive analysis of quantification uncertainty was undertaken. Using representative compounds, quantification uncertainties were found to be less than 37.67 %, 22.54 %, and 12.74 % for alkanes, polycyclic aromatic hydrocarbons (PAHs), and alkyl-substituted benzenes, respectively, across the GC × GC space, excluding the first and the last time intervals. From a source apportionment perspective, adamantane was clearly isolated as a potential tracer for heavy-duty diesel vehicle (HDDV) emissions. The systematic distribution of nitrogen-containing compounds in oxidized and reduced valences was discussed, and many of them served as critical tracers for secondary nitrate formation processes. The results highlighted the benefits of developing self-constructed models for the enhanced peak identification, automated cluster analysis, robust uncertainty estimation, and source apportionment and achieving the full potential of GC × GC–MS in atmospheric chemistry. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
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