| Abstrakt: |
In this study, we compare synergistic performance of two different nanofillers, namely halloysite nanotubes (HNT) clay and multiwalled carbon nanotubes (MWCNT), in conjunction with a fixed concentration (0.125 phr) of semi‐anthracite coal‐derived graphene oxide (AC‐GO) on mechanical properties improvement of EGFPs (E‐glass fiber‐based epoxy resin composites). The dispersion of AC‐GO with HNT clay (GO‐H) and AC‐GO with MWCNT (GO‐C) within epoxy matrix was achieved using sonication and homogenization. Further mixture was incorporated into mats of E‐glass fiber employing "vacuum‐assisted resin infusion molding" (VARIM). Significant enhancements (18.3% flexural strength, 14.6% tensile strength, and a slight increase of impact strength (1.8%)) were observed in EGFPs reinforced with GO‐H at 0.50 phr loading of HNT, with an AC‐GO concentration maintained at 0.125 phr. Correspondingly, optimal values for GO‐C reinforced EGFPs at 0.25 phr were 40.3%, 18.7%, and a 10.5% decrease in impact strength, respectively. Analytical techniques such as XRD, FESEM, EDX mapping, and FTIR reveal presence of relatively abundant functionalities and strong interfacial adhesion in GO‐H as well as GO‐C. The cost of HNT clay is approximately 15 times cheaper than industrial‐grade MWCNTs, therefore, these results underscore potential of GO‐H as a very economical nano‐reinforcement alternative to GO‐C for polymer nanocomposites. Highlights: 0.50 phr HAGRP improves 18.3% flexural, 14.6% tensile, 1.8% impact strengths.Beyond 0.50 phr HAGRP and 0.25 phr CAGRP, mechanical properties decreased.0.25 phr CAGRP improves 40.3% flexural, and18.7% tensile strengths.FESEM, FTIR reveal strong interfacial adhesion between nanofillers and epoxy.GO‐H has proven to be an inexpensive reinforcement for polymer nanocomposites. [ABSTRACT FROM AUTHOR] |
Plný text