| Autor: |
Yu, Xiang, Li, Lin, Gao, Jincheng, Liu, Yuquan, Yuan, Ze, Yao, Minghai, Liu, Yang, Zhou, Huamin |
| Předmět: |
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| Zdroj: |
Advanced Functional Materials; 9/18/2024, Vol. 34 Issue 38, p1-7, 7p |
| Abstrakt: |
Dielectric polymers are essential to capacitive capacitors widely used in modern electronic and electrical systems. Most useful dielectric polymers are derived from petroleum while environmentally sustainable dielectric biomass remains mostly unexplored although they are abundant, renewable, and cost‐effective. Here an ultrahigh energy density in cyanoethyl cellulose (CEC) and cyanoethyl pullulan (CEP) obtained by replacing the hydroxyl groups of cellulose and pullulan with cyanoethyl is reported. Large dielectric constants of 16.7 and 20.0 in CEC and CEP due to the strong polarity of cyanoethyl which are comparable to high‐dielectric ferroelectric polymers are shown. CEC and CEP show nearly no degradation of the dielectric constant with increasing electric fields, inhabiting the early polarization saturation and thus leading to improved energy density, which is different from relaxor ferroelectric polymers. Consequently, solution‐processable CEP films exhibit an ultrahigh discharged energy density of 28.2 J cm−3 with an efficiency of 72% at 600 MV m−1, outperforming other all‐organic dielectric biomass materials. The work paves the way for the development of high‐performance dielectric biomass for energy storage applications. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
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