Exploring Imidazole Binding Flexibility in 2D and 3D Frameworks Using Hypercoordinated Triorganotin Carboxylates Featuring a Nitrogen-Rich Ligand with Benzoic Acid, Diazenyl, and Imidazole Functionalities: Insights into Sn − N, N → Sn, and N − H⋅⋅⋅X (X = N, O) Interactions†

Autor: Basu Baul, Tushar S., Hlychho, Bietlaichhai, Manne, Rajesh, Lyčka, Antonin, Schollmeyer, Dieter, Jurkschat, Klaus, Mahmoud, Abdallah G., Guedes da Silva, M. Fátima C., Vasquez-Ríos, María G., Höpfl, Herbert
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Zdroj: Journal of Inorganic & Organometallic Polymers & Materials; Jul2024, Vol. 34 Issue 7, p3281-3299, 19p
Abstrakt: The multitopic heterofunctional pro-ligand 4-[(E)-(1H-imidazol-2-yl)diazenyl]benzoic acid (H′HL) was synthesized by diazotization of 4-aminobenzoic acid followed by coupling with imidazole. Reactions of H′HL (where H = imidazole proton and H′ = carboxylic acid proton) with the triorganotin precursors nPr3SnCl, (nBu3Sn)2O and Ph3SnOH provided three hypercoordinated triorganotin complexes, viz., [nPr3Sn(μ4-L)SnnPr3]n⋅1/8nEtOH (1), [nBu3Sn(μ-HL)]n (2) and [Ph3Sn(HL)]⋅0.5C6H6 (3), with complex 2D and 3D frameworks based on Sn − O, O → Sn, Sn − N and N → Sn metal–ligand bonds as well as N − H⋅⋅⋅N, N − H⋅⋅⋅O and π-interactions. The compositions and structures of 1–3 in solution and in the solid-state were unambiguously established by NMR (1H, 13C, 119Sn) and IR spectroscopy, UV‒Vis spectral analysis, high-resolution mass spectrometry (HRMS) and single-crystal X-ray diffraction (scXRD) studies accompanied by Hirshfeld surface maps and 2D fingerprint plots. The binding potential of a heterotopic ligand carrying strong metal-coordinating carboxylate and imidazole functions and a color-providing diazenyl group, all embedded in an overall planar skeleton, was examined in 1:1 and 1:2 combinations with triorganotin moieties, yielding the frameworks illustrated in the graphical abstract. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
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