| Autor: |
SHINOHARA, TADATOMI, SMALLEY, MARTIN V., SOGAMI, IKUO S. |
| Předmět: |
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| Zdroj: |
International Journal of Modern Physics B: Condensed Matter Physics; Statistical Physics; Applied Physics; 8/10/2005, Vol. 19 Issue 20, p3217-3241, 25p |
| Abstrakt: |
The Gibbs free energy of two highly charged plates immersed in an electrolyte solution in a finite container is investigated using mean field theory. Adiabatic potential of the charged plates, which is derived from the Gibbs free energy, has a long-range weak attractive part and medium range strong repulsive part under the Dirichlet boundary condition. From comparison with the Helmholtz adiabatic potential, it is proved that the two adiabatic potentials have qualitatively the same structure of a repulsive component and an attractive component and that the Gibbs adiabatic potential shows the stronger attractive effect. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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