| Autor: |
Bathula, Ganesh Babu, Gopal, N. O., Chelimela, Narsaiah, Kurra, Mohan, kumar goud, S. Sharat, Nimma, Rameshwar, Mavurapu, Satyanarayana, B, Jonnalagadda S., Vasam, Chandra Sekhar |
| Předmět: |
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| Zdroj: |
Oriental Journal of Chemistry; Aug2024, Vol. 40 Issue 4, p920-932, 13p |
| Abstrakt: |
This review article describes the designing and aptness of diverse range of cerium-based catalysts for the oxidation of benzyl alcohols (Bz-OLs) in producing exclusively benzaldehydes (Bz-ALs) in the presence of eco-friendly oxidants. The discussion highlights the significance of surface and structural properties inherent to cerium-based catalysts, including the abundance of oxygen vacancies, the redox properties of Ce3+/Ce4+ couple, their acid-base characteristics and morphology influence, which play crucial roles in substrate adsorption, reorganization of bonding between substrate and oxidant in promoting selective oxidation reactions. The consolidated data tables (1-4) comprising the best conditions optimized with various ceria based heterogeneous reported so far between the years 2019-2024 is included in the following sections to assess the catalyst design and performance. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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