Autor: |
He, Bin, Chen, Gen-Qiang, Zhang, Xumu |
Předmět: |
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Zdroj: |
Chemical Communications; 9/16/2024, Vol. 60 Issue 72, p9785-9788, 4p |
Abstrakt: |
A novel synthetic route was developed for the construction of chiral cis-vicinal halohydrins derivatives through Ir/f-phamidol-catalysed asymmetric hydrogenation of corresponding α-halogenated ketones with high yields (up to 99% yield), excellent diastereoselectivities (>20 : 1 dr), enantioselectivities (up to 99% ee), and high substrate catalyst ratio (S/C = 1000). [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
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