Ti-catalyzed homocyclomagnesiation of (Z)-1,2,6-trienes in the stereoselective synthesis of 1Z,5Z,9Z,13Z-tetraenes.

Autor:	Makarova, E. Kh., Makarov, A. A.
Předmět:	STEREOSELECTIVE reactions ALLENE
Zdroj:	Russian Chemical Bulletin; Jul2024, Vol. 73 Issue 7, p1916-1922, 7p
Abstrakt:	On the basis of the Ti-catalyzed homocyclomagnesiation of terminal 1,2-dienes, an effective method for the synthesis of 1Z,5Z,9Z,13Z-tetraenes in high yields and high stereoselectivity has been developed. A new approach to the synthesis of allenes with substituents containing Z-double bonds has been elaborated. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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