| Autor: |
Li, Xiaohong, Wang, Shenfan, Fu, Xiangxiang, Xing, Donghui, Fu, Zeyuan, Deng, Yuanfu, Jiang, Huanfeng, Huang, Liangbin |
| Zdroj: |
SCIENCE CHINA Chemistry; Sep2024, Vol. 67 Issue 9, p2975-2981, 7p |
| Abstrakt: |
Herein, a nickel-catalyzed arylcyanation of unactivated alkenes via cyano group translocation with aryl boronic acids has been developed. These transformations provided a robust approach to constructing structurally diverse 1,n-dinitriles or 4-amino nitriles from easily prepared and commercially available starting materials. The cyano group translocation was achieved, involving the addition into the intramolecular C–N triple bond followed by the retro-Thorpe reaction. Mechanistic studies revealed that high temperature and CsHCO3 as the base were crucial for the cyano group translocation. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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