Whitening of Aluminum Surface by Anodizing at High Current Density in Sulfuric Acid Solution.

Autor: Tomo Hariyama, Kazunobu Ito, Teruyoshi Saito, Sumitaka Watanabe, Sachiko Ono
Předmět:
Zdroj: Materials Transactions; 2024, Vol. 65 Issue 8, p954-960, 7p
Abstrakt: In this study, we examined a method for whitening an aluminum surface by anodizing it in a sulfuric acid solution to industrialize the process. Anodic oxidation in a sulfuric acid solution at 2.5Adm-2 for 120 s resulted in the whitening of the aluminum surface, but localized burning occurred. When anodization was performed at a low current density for a short time (2.5Adm-2 for 4.5 s) after a high current density, a white anodic film was successfully obtained without burning. Cross-sectional scanning electron microscopy (SEM) observation of the white film revealed that etching by pretreatment created an uneven surface, and pore branching created an uneven metal-oxide interface. The fluctuating value of the film thickness obtained by length measurements using SEM was 0.2-0.3 µm. This value is sufficient to whiten the anodic film because of increase in diffusion reflection at the film surface and the metal-oxide interface. These results indicate that the difference in the peak voltage between the first and second anodizing resulted in the formation of a branched pore structure and film whitening. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index