| Abstrakt: |
In this study, poly(butylene adipate‐co‐terephthalate) (PBAT) biocomposites were generated from spent coffee grounds (SCGs) or torrefied SCG (TSCGs) using a melt compounding process. TSCGs were obtained at torrefaction temperatures of 230, 245, 260, 275, or 290°C for a duration of 60 min. Torrefaction enhanced the hydrophobicity, grindability, and biomass stability of the resulting composites by eliminating hemicellulose. Various concentrations of SCGs (10 and 20 wt.%) and TSCGs (10, 20, and 30 wt.%) were compounded into PBAT. The thermal, mechanical, and degradation properties of PBAT biocomposites were investigated. As SCGs and TSCGs were introduced, the crystallization temperature drastically increased. Compared with PBAT biocomposites with SCGs, PBAT biocomposites with TSCGs exhibited higher thermal stability and hydrophobicity, and improved mechanical properties. Further, alkaline hydrolysis occurred at a faster rate for biocomposites with biofillers than for neat PBAT. Therefore, this study demonstrated the improved compatibility between SCGs and PBAT by torrefaction. [ABSTRACT FROM AUTHOR] |
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