| Autor: |
Gao, Junfang, Xu, Shixun, Zhang, Li, Hu, Gang, Shi, Shenggang, Liu, Lu, Yang, Junhong |
| Předmět: |
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| Zdroj: |
Journal of Coordination Chemistry; Jun/Jul2024, Vol. 77 Issue 12-14, p1500-1510, 11p |
| Abstrakt: |
This work used an aqueous-phase method to prepare Sm-doped CdTe nanocrystals (NCs). The successful doping of Sm into the CdTe lattice was confirmed by powder X-ray diffraction (PXRD), transmission electron microscopy (TEM), as well as UV–Visible (UV–Vis) absorption and emission spectroscopies. The CdTe and CdTe:Sm NCs are monodispersed as uniform spherical nanocrystals with cubic structures. The particle diameters are ∼4.2, ∼3.3, and ∼2.6 nm for CdTe, CdTe:Sm(5%) and CdTe:Sm(10%) NCs, respectively. Compared with pure CdTe, the CdTe:Sm(5%) NCs exhibit a blueshift of 9–23 nm in their absorption bands and a blueshift of 8–17 nm in their emission bands. With increasing concentration of Sm3+, the quantum yield (QY) of the CdTe:Sm NCs increases initially and then decreases. The CdTe:Sm NCs have longer fluorescence lifetimes than CdTe, probably due to the introduction of trap states. Due to charge compensation, the CdTe:Sm NCs have much stronger emission peaks. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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