Effect of a Substitute in a Ligand and a Counterion on the Properties of a Heptanuclear Mixed-Valence Iron Complex.

Autor: Batueva, E. E., Sharipova, A. R., Frolova, E. N., Savostina, L. I., Bazan, L. V., Cherosov, M. A., Batulin, R. G., Turanova, O. A., Turanov, A. N.
Zdroj: Bulletin of the Russian Academy of Sciences: Physics; Jul2024, Vol. 88 Issue 7, p1153-1157, 5p
Abstrakt: New heptanuclear mixed-valence iron complexes with pentadentate ligands are synthesized, and their magnetic properties are analyzed. Magnetometry and EPR show that thiocyanate anions promote spin-crossover properties. Introducing long alkoxy chains into a molecule gives it thermotropic liquid crystalline properties and enhances its cooperative magnetic properties. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
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