| Autor: |
Balanov, Mikhail I., Emeline, Alexei V., Shtarev, Dmitry S. |
| Předmět: |
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| Zdroj: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 9/7/2024, Vol. 53 Issue 33, p13764-13781, 18p |
| Abstrakt: |
In the presented work, the structure dependence as well as luminescence features of a wide range of hybrid crystals based on lead halides and a homologous series of alkyl diamines from 1,4-diaminobutane to 1,8-diaminooctane are investigated. The structure of several previously undescribed hybrid crystals has been established. The even–odd effect of alkanes and its influence on the structure of such hybrid crystals have been demonstrated for the first time. The luminescence properties of the crystals and their dependence on the type of anion as well as the length and oddity of the organic cation are described in detail. The obtained data expand our knowledge of the relationship between the structure of the organic cation, including its parity and structure, and the electronic and optical properties of the hybrid crystals. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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