| Autor: |
Ping-Xin Wu, Chun-Xia Chen, Yan-Qiong Sun, Shou-Tian Zheng |
| Předmět: |
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| Zdroj: |
Chemical Communications; 8/28/2024, Vol. 60 Issue 67, p8888-8891, 4p |
| Abstrakt: |
A rare all-inorganic high-nuclearity mixed-valent {Mn11} cluster embedded polyoxoniobate, K25H43{(Te4Nb9O33)3(Nb6O19)5(TeVI-Nb5O14)[(TeIVO3)2(MnII7MnIII4 O19)]}•97H2O (1), has been synthesized by a one-pot reaction. Compound 1 contains the largest manganese cluster {Mn11} core among polyoxoniobates reported to date. {Mn11} consists of three quasi-cubane {Mn3O4} units and is simultaneously encapsulated by lacunary α-Keggin {Te4Nb9O36} and Lindqvist {Nb6O19} units. Compound 1 exhibits significant magnetic anisotropy and excellent water solubility and stability. The findings suggest a new, all-inorganic polynulear Mn-based structural paradigm for aqueous solution chemistry and magnetic materials. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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